[ACIE] 我室夏海平教授、朱军教授和吕鑫教授发表论文:Synthesis and Characterization of a Metallacyclic Framework with Three Fused Five-membered Rings

我室夏海平教授、朱军教授和吕鑫教授在 ACIE 发表论文:Synthesis and Characterization of a Metallacyclic Framework with Three Fused Five-membered Rings

文章链接:http://onlinelibrary.wiley.com/doi/10.1002/anie.201704057/full

摘要:

Polycyclic complexes containing a bridgehead transition metal are interesting species because the transition metal is shared by all the rings simultaneously. In this study, we present a novel osmium–bridgehead system with three fused five-membered rings. This novel framework can be viewed as a 10-atom carbon chain coordinating to the osmium center. In sharp contrast to the nonplanar organic analogue, this unique metallacycle exhibits good planarity, which was unambiguously verified by means of X-ray diffraction. Interestingly, preliminary DFT calculations show that the aromaticity in the three 5MRs of these osmatricycles can be easily tuned by the ligand substitution. Finally, the broad UV/Vis absorption spectra of these novel polycyclic complexes were also reported.